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Synthesis, Structure, and Properties of Cadmium(II) Centered Chiral Coordination Polymer based on ( R )‐6‐(1‐Carboxyethoxy)‐2‐naphthoic Acid
Author(s) -
Wang XiuWen,
Huang JiHan,
Wang JunKu,
Yu YingHui,
Ma DongSheng
Publication year - 2019
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201900029
Subject(s) - thermogravimetric analysis , luminescence , powder diffraction , crystallography , infrared spectroscopy , cadmium , elemental analysis , coordination polymer , materials science , circular dichroism , polymer , diffraction , hydrothermal synthesis , crystal structure , chemistry , hydrothermal circulation , inorganic chemistry , physics , organic chemistry , chemical engineering , optics , optoelectronics , metallurgy , composite material , engineering
A cadmium chiral coordination polymer, formulated as [Cd(R‐cna)] n ( 1 ‐D) was constructed under hydrothermal method. Single‐crystal X‐ray diffraction analysis indicated that 1 ‐D exhibited a 2D layered structure with a point symbol of (4 7 · 6 3 ). 1 ‐D was further characterized by infrared spectra, powder X‐ray diffraction (PXRD), elemental analysis, thermogravimetric analysis (TGA), and circular dichroism spectra (CD). The second‐harmonic generation (SHG) property was investigated. It was also found that the luminescence of 1 ‐D can be quenched by iron ions and trinitrotoluene, indicating its potential application as luminescence sensing material.