Premium
Synthesis and X‐ray Crystal Structures of Ru 3 (CO) 9 (μ‐arphos)(L) [L = AsPh 3 , As( m ‐C 6 H 4 Me) 3 , As( p ‐C 6 H 4 Me) 3 ]
Author(s) -
Syaida Sirat Siti,
Shawkataly Omar Bin
Publication year - 2019
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201900013
Subject(s) - crystallography , chemistry , crystal structure , x ray crystallography , single crystal , arsine , ruthenium , spectroscopy , x ray , diffraction , catalysis , phosphine , physics , quantum mechanics , optics , biochemistry
Three new triruthenium clusters, Ru 3 (CO) 9 (μ‐arphos)AsPh 3 ( 1 ), Ru 3 (CO) 9 (μ‐arphos)As( m ‐C 6 H 4 Me) 3 ( 2 ), and Ru 3 (CO) 9 (μ‐arphos)As( p ‐C 6 H 4 Me) 3 ( 3 ) were synthesized via thermal reactions of Ru 3 (CO) 10 (μ‐arphos) with different tertiary arsine ligands [AsPh 3 , As( m ‐C 6 H 4 Me) 3 , As( p ‐C 6 H 4 Me) 3 ]. All these complexes were fully characterized by elemental analysis, FT‐IR, NMR spectroscopy, and single‐crystal X‐ray diffraction.