Premium
Palladium(II) Incorporation in the All‐Inorganic Cryptand [As 4 W 40 O 140 ] 28– : Synthesis and Structural Characterization of [Pd 2 Na 2 KAs 4 W 40 O 140 (H 2 O)] 21–
Author(s) -
Lin Zhengguo,
Izarova Natalya V.,
Mehari Fitsumbirhan T.,
Kortz Ulrich
Publication year - 2018
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201800327
Subject(s) - palladium , chemistry , crystal structure , cryptand , potassium , single crystal , nuclear chemistry , inorganic chemistry , infrared spectroscopy , elemental analysis , crystallography , catalysis , organic chemistry , ion
The palladium(II)‐containing 40‐tungsto‐4‐arsenate(III) [Pd 2 Na 2 KAs 4 W 40 O 140 (H 2 O)] 21– ( 1a ) was synthesized by reaction of PdSO 4 with the cryptate heteropolyanion [As 4 W 40 O 140 ] 28– in potassium acetate buffer. The title compound was characterized by single‐crystal XRD, IR, TGA, and elemental analysis.