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Fe 2 O 3 ‐N‐doped Honeycomb‐like Porous Carbon Derived from Nature Silk Sericin as Electrocatalysts for Oxygen Evolution Reaction
Author(s) -
Li Changqing,
Zhao Tao,
Yassin Hussain Abdalkarim Somia,
Wu Yuhang,
Lu Mengting,
Li Yuwen,
Gao Junkuo,
Yao Juming
Publication year - 2018
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201800325
Subject(s) - overpotential , tafel equation , electrocatalyst , materials science , carbon fibers , oxygen evolution , catalysis , chemical engineering , inorganic chemistry , chemistry , electrochemistry , composite number , composite material , electrode , organic chemistry , engineering
A facile method is reported to form a honeycomb‐like porous nanomaterial by intercalation of iron nitrate using nature silk sericin (SS) as nitrogen and carbon source. A series of Fe 2 O 3 nanoparticles anchored on Fe 2 O 3 ‐N‐doped graphite carbon electrocatalysts (SS‐Fe) were synthesized, exhibits well‐defined pore structure and excellent oxygen evolution reaction (OER) catalytic activities. Among these materials, SS‐Fe‐0.5 shows the best performance, the overpotential of SS‐Fe‐0.5 at 10 mA · cm –2 is 440 mV (vs. RHE) and the Tafel slope is only 68 mV · dec –1 . The results indicate that it is promising to the preparation of carbon catalyst materials using natural, renewable and abundant resources for electrocatalysis.