Ligand Mediated Morphology of the Two‐Dimensional Uranyl Aqua Sulfates [UO 2 ( X )(SO 4 )(H 2 O)] [X = Cl –  or (CH 3 ) 3 NCH 2 COO] | Zendy

Smith Philip A. | Zendy; Burns Peter C. | Zendy

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Ligand Mediated Morphology of the Two‐Dimensional Uranyl Aqua Sulfates [UO 2 ( X )(SO 4 )(H 2 O)] [X = Cl – or (CH 3 ) 3 NCH 2 COO]

Author(s) -

Smith Philip A.,

Burns Peter C.

Publication year - 2019

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201800320

Subject(s) - uranyl , crystallography , chemistry , crystal structure , ligand (biochemistry) , x ray crystallography , morphology (biology) , sulfate , hydrothermal synthesis , stereochemistry , hydrothermal circulation , ion , diffraction , organic chemistry , chemical engineering , biochemistry , physics , receptor , biology , optics , genetics , engineering

Two uranyl aqua sulfate compounds: [(CH 3 ) 3 NCH 2 COOH] [UO 2 (Cl)(SO 4 )(H 2 O)] ( 1 ) and UO 2 ((CH 3 ) 3 NCH 2 COO)(SO 4 )(H 2 O) ( 2 ) were synthesized and their crystal structures were determined. The morphology changes between the two‐dimensional anionic structural unit of 1 and the neutral structural unit of 2 are examined, and the impact of their terminally coordinating ligands discussed.

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