(C 4 C 1 Im) 6 [Hg 7 Se 10 ]: The Salt of a Molecular Selenido Mercurate Anion Obtained from Ionic Liquids | Zendy

Donsbach Carsten | Zendy; Dehnen Stefanie | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

(C 4 C 1 Im) 6 [Hg 7 Se 10 ]: The Salt of a Molecular Selenido Mercurate Anion Obtained from Ionic Liquids

Author(s) -

Donsbach Carsten,

Dehnen Stefanie

Publication year - 2018

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201800277

Subject(s) - ionic liquid , ternary operation , salt (chemistry) , ion , chemistry , substructure , crystallography , ionic bonding , crystal structure , spectroscopy , analytical chemistry (journal) , chromatography , organic chemistry , catalysis , physics , structural engineering , quantum mechanics , computer science , engineering , programming language

A binary selenido mercurate anion exhibiting a novel metalate topology was obtained as its salt (C 4 C 1 Im) 6 [Hg 7 Se 10 ] ( 1 ) upon treatment of the ternary selenido mercurate K 2 [Hg 2 Se 3 ] in the ionic liquid (C 4 C 1 Im)[BF 4 ] (C 4 C 1 Im = 1‐butyl‐3‐methylimidazolium) in the presence of small amounts of 1,2‐diaminoethane (en) at slightly elevated temperatures (80 °C). The three‐dimensionally extended anionic substructure was disassembled this way with formation of the unprecedented heptanuclear anion [Hg 7 Se 10 ] 6– . The light yellow crystals of 1 are extremely sensitive to air and moisture. The structure of 1 was determined by single‐crystal X‐ray diffraction, and its heavy element composition was analyzed and confirmed by micro X‐ray fluorescence spectroscopy (μ‐XFS).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research