A Ferrocenyl Amino Substituted Stannylene as an Intramolecular Fe→Sn Lewis Adduct | Zendy

Förster Christoph | Zendy; Becker Patrick M. | Zendy; Heinze Katja | Zendy

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A Ferrocenyl Amino Substituted Stannylene as an Intramolecular Fe→Sn Lewis Adduct

Author(s) -

Förster Christoph,

Becker Patrick M.,

Heinze Katja

Publication year - 2018

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201800269

Subject(s) - lewis acids and bases , intramolecular force , adduct , chemistry , tin , density functional theory , solid state , crystallography , stereochemistry , atom (system on chip) , metal , medicinal chemistry , computational chemistry , organic chemistry , catalysis , computer science , embedded system

The acyclic ferrocenyl amino substituted stannylene Sn[N(Fc)SiMe 3 ] 2 1 was synthesized from tin(II) chloride and in situ formed LiN(Fc)(SiMe 3 ). The molecular structure of 1 in the solid state shows two short intramolecular Fe ··· Sn contacts suggesting electron donation of the iron(II) atoms to the tin(II) atom as double intramolecular metal‐only Lewis base/Lewis acid adduct. Density functional theory (DFT) calculations support this Fe→Sn stabilizing effect.

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