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Preparation and Molecular Structure of a Series of Bicyclic [3]Ferrocenophanes Containing Pb 2 P 2 Bridges
Author(s) -
Kargin Denis,
Krekić Kristijan,
Pietschnig Rudolf
Publication year - 2018
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201800239
Subject(s) - bicyclic molecule , zigzag , nucleophile , chemistry , crystallography , electrophile , nuclear magnetic resonance spectroscopy , stereochemistry , solubility , x ray crystallography , crystal structure , diffraction , organic chemistry , physics , catalysis , geometry , mathematics , optics
Phosphanyl‐substituted plumbylenes can be embedded into a [3]ferrocenophane scaffold giving rise to bicyclic ferrocenophanes Fe(C 5 H 4 P t BuPb X ) 2 ( X = Cl, Br, Mes, OMes*). The electrophilic nature of the phosphanylhaloplumbylenes may be exploited to add nucleophiles resulting in zigzag‐like haloplumbate strands. All compounds were characterized by single‐crystal X‐ray diffraction and with multinuclear NMR spectroscopy solubility and stability permitting.