Tetrafluoridonitridotechnetate(VI) – Reactions and Structures | Zendy

Balasekaran S. Mariappan | Zendy; Hagenbach Adelheid | Zendy; Abram Ulrich | Zendy

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Tetrafluoridonitridotechnetate(VI) – Reactions and Structures

Author(s) -

Balasekaran S. Mariappan,

Hagenbach Adelheid,

Abram Ulrich

Publication year - 2018

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201800206

Subject(s) - electron paramagnetic resonance , aqueous solution , paramagnetism , dissolution , ion , diamagnetism , chemistry , inorganic chemistry , nuclear chemistry , crystallography , nuclear magnetic resonance , organic chemistry , physics , quantum mechanics , magnetic field

Dissolution of the polymeric nitridotechnetic(VI) acid in aqueous HF results in the formation of the [TcNF 4 ] – anion. The presence of the paramagnetic anion in such solutions can readily be confirmed by EPR spectroscopy. Addition of CsF or (NEt 4 )F gives orange‐yellow, diamagnetic solids of the compositions Cs 3 (NH 4 )[F 4 NTc(μ‐O)TcNF 4 ] and (NEt 4 ) 3 (NH 4 )[NF 2 Tc(μ‐O) 2 TcNF 2 ] 2 , respectively.

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