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Structure and Electronic Properties of an Expanded Terpyridine Complex of Nickel(II) [Ni(ddpd) 2 ](BF 4 ) 2
Author(s) -
Dorn Matthias,
Mack Katharina,
Carrella Luca M.,
Rentschler Eva,
Förster Christoph,
Heinze Katja
Publication year - 2018
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201800101
Subject(s) - nickel , terpyridine , ligand (biochemistry) , ligand field theory , electrochemistry , solid state , diamine , crystallography , materials science , electronic structure , chemistry , computational chemistry , polymer chemistry , metallurgy , metal , organic chemistry , electrode , ion , biochemistry , receptor
The synthesis, structure in the solid state, electrochemical, magnetic and optical properties of a new nickel(II) complex [Ni(ddpd) 2 ] 2+ bearing the tridentate N , N ′‐dimethyl‐ N , N ′‐dipyridin‐2‐ylpyridine‐2,6‐diamine (ddpd) ligand are presented. The optical properties are discussed within the framework of ligand field theory.