Post‐synthetic Modification of a Dinuclear Spin Crossover Iron(III) Complex | Zendy

Komatsumaru Yuki | Zendy; Nakaya Manabu | Zendy; Kobayashi Fumiya | Zendy; Ohtani Ryo | Zendy; Nakamura Masaaki | Zendy; Lindoy Leonard F. | Zendy; Hayami Shinya | Zendy

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Post‐synthetic Modification of a Dinuclear Spin Crossover Iron(III) Complex

Author(s) -

Komatsumaru Yuki,

Nakaya Manabu,

Kobayashi Fumiya,

Ohtani Ryo,

Nakamura Masaaki,

Lindoy Leonard F.,

Hayami Shinya

Publication year - 2018

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201800087

Subject(s) - spin crossover , magnetic susceptibility , chemistry , crystallography , mössbauer spectroscopy , spectral line , spin (aerodynamics) , materials science , physics , thermodynamics , astronomy

The dinuclear iron(III) complex [Fe(salten) 2 (bipytz)](BPh 4 ) 2 · EtOH ( 1 ) was synthesized and its post‐synthesis modification yielded [Fe(salten) 2 (bipydz)](BPh 4 ) 2 · EtOH ( 2 ). The crystal structures and magnetic behaviors of 1 and 2 were investigated by variable temperature XRD, magnetic susceptibility, and Mössbauer spectra measurements, with each of these dinuclear iron(III) complexes exhibiting gradual spin crossover behavior.

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