The First Molybdenum Oxo‐iodide Cluster – [Mo 4 OI 12 ] 2– | Zendy

Mikhaylov Maxim A. | Zendy; Abramov Pavel A. | Zendy; Novozhilov Igor N. | Zendy; Sokolov Maxim N. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

The First Molybdenum Oxo‐iodide Cluster – [Mo 4 OI 12 ] 2–

Author(s) -

Mikhaylov Maxim A.,

Abramov Pavel A.,

Novozhilov Igor N.,

Sokolov Maxim N.

Publication year - 2018

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201800053

Subject(s) - molybdenum , diglyme , chemistry , cluster (spacecraft) , iodide , raman spectroscopy , crystallography , ion , crystal structure , salt (chemistry) , mass spectrometry , infrared spectroscopy , inorganic chemistry , physics , organic chemistry , solvent , computer science , optics , programming language , chromatography

Reaction of Mo(CO) 6 with Bu 4 NI and I 2 in diglyme yielded a new butterfly Mo III cluster [Mo 4 OI 12 ] 2– . The structure of tetraphenylphosphonium salt was determined by X‐ray single crystal diffraction. Ph 4 P + and Bu 4 N + salts were further characterized by elemental analysis, mass spectrometry, energy‐dispersive X‐ray (EDX), IR, Raman, and UV/Vis spectroscopy and CVA studies. The cluster anion has a butterfly array of molybdenum atoms and can be represented as [Mo 4 (μ 4 ‐O)(μ 3 ‐I) 2 (μ 2 ‐I 4 )I 6 ] 2– .

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research