Premium
Syntheses of Transition Metal Complexes of Pentafluorophenylhydrazine
Author(s) -
Rieber Wolfram,
Beck Wolfgang
Publication year - 2018
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201800010
Subject(s) - transition metal , chemistry , metal , medicinal chemistry , inorganic chemistry , catalysis , organic chemistry
By reaction of pentafluorophenylhydrazine with metal chlorides the complexes M (NH 2 NHC 6 F 5 ) 4 Cl 2 ( M = Co, Ni), M (NH 2 NHC 6 F 5 ) 2 Cl 2 ( M = Mn, Fe, Pd, Zn, Cd), Cu(NH 2 NHC 6 F 5 )Cl, and Hg(NH 2 NHC 6 F 5 ) 2 Cl were obtained. From Cr(CO) 6 and pentafluorophenylhydrazine the complex Cr(CO) 5 (NH 2 NHC 6 F 5 ) was synthesized.