Front Cover: Structural Characterization of (Arylimido)vanadium(V) Compounds with 2,6‐Difluorophenoxide Ligand (Z. Anorg. Allg. Chem. 18/2017) | Zendy

Moriuchi Toshiyuki | Zendy; Sakuramoto Takashi | Zendy; Nishina Masafumi | Zendy; Kawai Ryota | Zendy; Hirao Toshikazu | Zendy

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Front Cover: Structural Characterization of (Arylimido)vanadium(V) Compounds with 2,6‐Difluorophenoxide Ligand (Z. Anorg. Allg. Chem. 18/2017)

Author(s) -

Moriuchi Toshiyuki,

Sakuramoto Takashi,

Nishina Masafumi,

Kawai Ryota,

Hirao Toshikazu

Publication year - 2017

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201770181

Subject(s) - vanadium , front cover , ligand (biochemistry) , crystallography , crystal structure , bridging (networking) , chemistry , bridging ligand , stereochemistry , materials science , cover (algebra) , inorganic chemistry , receptor , engineering , computer science , mechanical engineering , computer network , biochemistry

The Front Cover shows molecular structures of (arylimido)vanadium(V) compounds. The (arylimido)vanadium(V) compounds bearing one or two 2,6‐difluorophenoxide ligands were found to form μ ‐isopropoxido‐bridged dimeric structures, wherein isopropoxide ligand was selectively employed as a bridging ligand between two vanadium centers. On the contrary, μ ‐phenoxido‐bridged dimeric structure was observed in (arylimido)vanadium(V) compound bearing three 2,6‐difluorophenoxide ligands. The absence of isopropoxide ligand leads to the μ ‐phenoxido‐bridging structure in the crystal packing. More details are discussed in the article by Moriuchi, Hirao et al. on pp. 1173 ff .

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