Premium
Front Cover: Structural Characterization of (Arylimido)vanadium(V) Compounds with 2,6‐Difluorophenoxide Ligand (Z. Anorg. Allg. Chem. 18/2017)
Author(s) -
Moriuchi Toshiyuki,
Sakuramoto Takashi,
Nishina Masafumi,
Kawai Ryota,
Hirao Toshikazu
Publication year - 2017
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201770181
Subject(s) - vanadium , front cover , ligand (biochemistry) , crystallography , crystal structure , bridging (networking) , chemistry , bridging ligand , stereochemistry , materials science , cover (algebra) , inorganic chemistry , receptor , engineering , computer science , mechanical engineering , computer network , biochemistry
The Front Cover shows molecular structures of (arylimido)vanadium(V) compounds. The (arylimido)vanadium(V) compounds bearing one or two 2,6‐difluorophenoxide ligands were found to form μ ‐isopropoxido‐bridged dimeric structures, wherein isopropoxide ligand was selectively employed as a bridging ligand between two vanadium centers. On the contrary, μ ‐phenoxido‐bridged dimeric structure was observed in (arylimido)vanadium(V) compound bearing three 2,6‐difluorophenoxide ligands. The absence of isopropoxide ligand leads to the μ ‐phenoxido‐bridging structure in the crystal packing. More details are discussed in the article by Moriuchi, Hirao et al. on pp. 1173 ff .