z-logo
Premium
Front Cover: High‐Pressure Synthesis and Single‐Crystal Structure Elucidation of the Indium Oxide‐Borate In 4 O 2 B 2 O 7 (Z. Anorg. Allg. Chem. 24/2017)
Author(s) -
Ortner Teresa S.,
Vitzthum Daniela,
Heymann Gunter,
Huppertz Hubert
Publication year - 2017
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201710241
Subject(s) - indium , boron , octahedron , oxide , front cover , crystallography , tetrahedron , materials science , cover (algebra) , high pressure , crystal structure , orange (colour) , chemistry , inorganic chemistry , mineralogy , metallurgy , physics , engineering physics , mechanical engineering , organic chemistry , engineering , food science
The Front Cover shows the indium oxide‐borate In 4 O 2 B 2 O 7 along the crystallographic c‐axis. This first representative of an oxide‐borate containing indium(III) is built up from bands of four, edge‐sharing InO 6 and InO 6+1 octahedra displayed in orange. These “orange bars”, formed by O 2‐ (blue) and In 3+ (yellow), are “stacked” alternatingly oriented in [1 1 0] and [110] – in the cover picture another of these elements is about to be added. Double‐tetrahedral B 2 O 7 units, shown in blue with centering B 3+ in red, interconnect the structure. As indicated by the “Score” achieved in this “Game”, In 4 O 2 B 2 O 7 is formed at 12.5 GPa and 1420 K using a Walker‐type multianvil apparatus. Details are discussed in the article by Hubert Huppertz et al. on page 2103 ff .

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here
Accelerating Research

Address

John Eccles House
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom