A Polymorphic Gold(III) Complex Comprising a Multifunctional Triazolylpropanamide Ligand | Zendy

Liebing Phil | Zendy; Wang Ling | Zendy; Gilje John W. | Zendy; Kühling Marcel | Zendy; Edelmann Frank T. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

A Polymorphic Gold(III) Complex Comprising a Multifunctional Triazolylpropanamide Ligand

Author(s) -

Liebing Phil,

Wang Ling,

Gilje John W.,

Kühling Marcel,

Edelmann Frank T.

Publication year - 2018

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201700456

Subject(s) - triclinic crystal system , monoclinic crystal system , hydrogen bond , supramolecular chemistry , ligand (biochemistry) , crystallography , thermal decomposition , chemistry , crystal structure , yield (engineering) , materials science , molecule , organic chemistry , metallurgy , biochemistry , receptor

Reaction of HAuCl 4 · 4H 2 O with the multifunctional ligand 3‐(1 H ‐1,2,4‐triazol‐1‐yl)propanamide ( 1 , TPA) afforded the polymorphic gold(III) complex AuCl 3 (TPA) ( 2 ) in 75 % yield. Thermal decomposition of the latter revealed the hydrochloride [HTPA]Cl ( 3 ). Complex 2 forms a stable monoclinic and a metastable triclinic modification. The crystal structures of both modifications feature infinite supramolecular assemblies formed by secondary Au ··· Cl bonding interactions and hydrogen bonding.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research