On Tungstates of Divalent Cations (I) – Structural Investigation and Spectroscopic Properties of Sr 2 [WO 5 ] and Ba 2 [WO 5 ] | Zendy

Jantz Stephan G. | Zendy; Pielnhofer Florian | Zendy; Dialer Marwin | Zendy; Höppe Henning A. | Zendy

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On Tungstates of Divalent Cations (I) – Structural Investigation and Spectroscopic Properties of Sr 2 [WO 5 ] and Ba 2 [WO 5 ]

Author(s) -

Jantz Stephan G.,

Pielnhofer Florian,

Dialer Marwin,

Höppe Henning A.

Publication year - 2017

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201700334

Subject(s) - raman spectroscopy , divalent , crystallography , luminescence , polyoxometalate , divalent metal , single crystal , tungstate , chemistry , crystal (programming language) , infrared spectroscopy , crystal structure , infrared , materials science , inorganic chemistry , physics , metal , optics , organic chemistry , programming language , optoelectronics , computer science , catalysis

The crystal structures of Sr 2 [WO 5 ] [ Pna 2 1 , a = 7.2457(3) Å, b = 10.8867(5) Å, c = 5.5391(3) Å, Z = 4, R int = 0.0671, R 1 = 0.0495, wR 2 = 0.0462] and Ba 2 [WO 5 ] [ Pnma, a = 7.3828(2) Å, b = 5.71420(10) Å, c = 11.4701(3) Å, Z = 4, R int = 0.0294, R 1 = 0.0146, wR 2 = 0.0284] are revised, based on single‐crystal XRD data. Furthermore spectroscopic data (infrared, Raman, and UV/Vis) assisted by DFT calculations are discussed and first results on the luminescence properties of Sr 2 [WO 5 ]:Eu 3+ are presented.

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