Premium
A Series of Homo‐ and Heteroleptic Iron(III) Alkoxides as Precursors for Fe 2 O 3
Author(s) -
Dietrich Stefan,
Finke Anita,
Fuhrmann Daniel,
Krautscheid Harald
Publication year - 2018
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201700332
Subject(s) - hematite , thermal decomposition , melting point , ligand (biochemistry) , chemistry , crystallography , decomposition , series (stratigraphy) , crystal structure , phase (matter) , inorganic chemistry , mineralogy , organic chemistry , geology , paleontology , biochemistry , receptor
A series of bulky iron(III) alkoxides was synthesized by a ligand exchange reaction using [Fe(O t Bu) 3 ] 2 and 2,4‐dimethylpentan‐3‐ol (H Odp ). The resulting complexes are dimers, structural details are compared based on single crystal structure analyses. Investigation of the thermal properties shows a decrease of the melting point upon exchange of the tert ‐butoxy by Odp – ligands. Thermolysis leads to volatile products and the formation of phase pure hematite.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom