Neutral and Cationic β‐Ketoiminato Bismuth Complexes | Zendy

Johnson Jobha A. | Zendy; Ashokan Arun | Zendy; Chalana Ashish K. | Zendy; Andrews Alex P. | Zendy; Venugopal Ajay | Zendy

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Neutral and Cationic β‐Ketoiminato Bismuth Complexes

Author(s) -

Johnson Jobha A.,

Ashokan Arun,

Chalana Ashish K.,

Andrews Alex P.,

Venugopal Ajay

Publication year - 2017

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201700054

Subject(s) - bismuth , cationic polymerization , homoleptic , chemistry , metathesis , salt metathesis reaction , salt (chemistry) , medicinal chemistry , stereochemistry , crystallography , polymer chemistry , organic chemistry , metal , polymerization , polymer

The first examples of neutral and cationic bismuth complexes bearing β‐ketoiminato ligands were isolated by employing salt metathesis route. BiCl 3 reacts with [O=C(Me)]CH[C(Me)N(K)Ar] ( 1 ) resulting in a homoleptic β‐ketoiminato bismuth complex Bi[{O=C(Me)}CH{C(Me)NAr}] 3 ( 2 ). The reaction between BiCl 3 and [(CH 2 ) 2 {N(K)C(Me)CHC(Me)=O} 2 ] ( 3 ) leads to the formation of a cationic bismuth complex [Bi{(CH 2 ) 2 (NC(Me)CHC(Me)=O) 2 }] 4 [Bi 2 Cl 10 ] ( 4 ).

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