A Selenium‐Nitrogen Chain with Selenium in Different Oxidation States | Zendy

Karhu Aino J. | Zendy; Jämsä Juho | Zendy; Rautiainen J. Mikko | Zendy; Oilunkaniemi Raija | Zendy; Chivers Tristram | Zendy; Laitinen Risto S. | Zendy

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A Selenium‐Nitrogen Chain with Selenium in Different Oxidation States

Author(s) -

Karhu Aino J.,

Jämsä Juho,

Rautiainen J. Mikko,

Oilunkaniemi Raija,

Chivers Tristram,

Laitinen Risto S.

Publication year - 2017

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201700031

Subject(s) - selenium , chemistry , molar ratio , nitrogen , chain (unit) , long chain , crystallography , inorganic chemistry , stereochemistry , organic chemistry , catalysis , polymer science , physics , astronomy

The reaction of t BuNH 2 with a mixture of SeCl 2 and SeOCl 2 in a 6:2:1 molar ratio produces the novel selenium‐nitrogen chain ClSeN( t Bu)Se(O)Cl ( 4 ), in which the selenium atoms are in two different oxidation states, Se II and Se IV . The crystal structure of 4 is compared with that of the related Se II /Se II system ClSeN( t Bu)SeCl ( 1 ) and differences are attributed to hyperconjugative effects. The energetics of the formation of 4 via two different routes are elucidated by PBE0/def2‐TZVPP calculations.

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