Arene Complexes of Divalent Tin Bromoaluminates | Zendy

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Arene Complexes of Divalent Tin Bromoaluminates

Author(s) -

Schleep Mario,

Ludwig Thilo,

Hettich Clarissa,

Leone Selina,

Krossing Ingo

Publication year - 2017

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201700018

Subject(s) - tin , counterion , divalent , chemistry , solvent , ion , crystallography , inorganic chemistry , stereochemistry , polymer chemistry , organic chemistry

Numerous arene complexes of tin(II) are well known with [AlCl 4 ] – as counterion, but none with the analogous [AlBr 4 ] – ion. Herein we report on new crystal structures containing arene complexes of tin and the tetrabromoaluminate anion obtained out of the reactions between SnBr 2 and AlBr 3 in the respective arene as solvent. Additionally, powder diffraction data and FIR spectra of the bulk products of these reactions are discussed.

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