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Arene Complexes of Divalent Tin Bromoaluminates
Author(s) -
Schleep Mario,
Ludwig Thilo,
Hettich Clarissa,
Leone Selina,
Krossing Ingo
Publication year - 2017
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201700018
Subject(s) - tin , counterion , divalent , chemistry , solvent , ion , crystallography , inorganic chemistry , stereochemistry , polymer chemistry , organic chemistry
Numerous arene complexes of tin(II) are well known with [AlCl 4 ] – as counterion, but none with the analogous [AlBr 4 ] – ion. Herein we report on new crystal structures containing arene complexes of tin and the tetrabromoaluminate anion obtained out of the reactions between SnBr 2 and AlBr 3 in the respective arene as solvent. Additionally, powder diffraction data and FIR spectra of the bulk products of these reactions are discussed.