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Cover Picture: ZAAC ‐ Journal of Inorganic and General Chemistry 8/2016
Author(s) -
Thi Ai,
Nhung Nguyen
Publication year - 2016
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201690007
Subject(s) - atomic orbital , cover (algebra) , molecular orbital , crystallography , physics , charge (physics) , chemistry , atomic physics , molecule , quantum mechanics , electron , mechanical engineering , engineering
The cover picture shows the circular blocks of Fe(CO) 4 complexes of Group‐13 half‐sandwich ligand ECp* with occupied orbitals of the molecules, the first circle consisting of Fe(CO) 4 ←ECp* σ‐type donor orbitals.The shape of the highest‐lying occupied orbitals, which have π‐ and σ‐symmetry of the ligands {ECp*}, are shown in the following circle.The outer circle shows the plots of the pairs of orbitals that yield the shape of NOCVs pairs, with the blue/red color indicating the sign of the orbitals and the yellow/white color in the deformation density designating charge depletion (the charge flow occurs in the direction from yellow to white). More details are discussed in the article by Thi Ai Nhung Nguyen et al. on pp. 609ff.