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Synthesis and Crystal Structures of Copper Zinc Phenylthiolate and the First Copper Zinc Selenolate and Tellurolate Complexes
Author(s) -
Fuhrmann Daniel,
Severin Tobias,
Krautscheid Harald
Publication year - 2017
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201600426
Subject(s) - copper , zinc , chemistry , crystal structure , inorganic chemistry , metallurgy , crystallography , materials science
Five copper zinc phenylchalcogenolate complexes [( i Pr 3 PCu) 3 (ZnMe 2 ) 2 (SPh) 3 ] ( 1 ), [( i Pr 3 PCu) 2 (ZnPh) 4 (SPh) 6 ] ( 2 ), [( i Pr 3 PCu) 2 (ZnEt) 4 (SPh) 6 ] ( 3 ), [( i Pr 3 PCu) 3 (ZnEt)(SePh) 4 ] ( 4 ), and [( i Pr 3 PCu) 3 Cu( i Pr 3 PZn)(TePh) 6 ] ( 5 ) were synthesized by the reaction of phosphine stabilized copper phenylchalcogenolate complexes with Zn R 2 ( R = Me, Et, Ph) with and without additional chalcogenol. The novel mixed metal compounds were characterized by single‐crystal X‐ray structure analysis and NMR spectroscopy. 4 and 5 are the first examples of compounds with a Zn–Se–Cu or a Zn–Te–Cu linkage, respectively.