N‐Heterocyclic Carbene Reactivity Towards Mercurous Chloride | Zendy

Roy Matthew M. D. | Zendy; Ferguson Michael J. | Zendy; Rivard Eric | Zendy

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N‐Heterocyclic Carbene Reactivity Towards Mercurous Chloride

Author(s) -

Roy Matthew M. D.,

Ferguson Michael J.,

Rivard Eric

Publication year - 2016

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201600304

Subject(s) - carbene , disproportionation , mercury (programming language) , adduct , halide , chemistry , chloride , halogen , solid state , reactivity (psychology) , medicinal chemistry , polymer chemistry , organic chemistry , catalysis , alkyl , medicine , alternative medicine , pathology , computer science , programming language

The synthesis and characterization of a novel dimeric N‐heterocyclic carbene ligated trimercury hexachloride adduct [(IPr)Hg 3 Cl 6 ] 2 [IPr = (HCNDipp) 2 C:; Dipp = 2,6‐ i Pr 2 C 6 H 3 ] is reported from the disproportionation reaction of IPr with mercury(I) chloride. The molecular structure of this species in the solid state represents a new bonding motif for a mercury halide.

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