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Syntheses and Structures of Zinc Bis(phosphinimino)methanide Complexes
Author(s) -
Bayram Melike,
Gondzik Sebastian,
Bläser Dieter,
Wölper Christoph,
Schulz Stephan
Publication year - 2016
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201600196
Subject(s) - heteronuclear molecule , zinc , crystallography , chemistry , spectroscopy , crystal structure , nuclear magnetic resonance spectroscopy , x ray crystallography , stereochemistry , diffraction , physics , organic chemistry , quantum mechanics , optics
Reactions of bis(phosphinimino)methanes H 2 C(PPh 2 N R ) 2 [ R = SiMe 3 (L 1 H), Ph (L 2 H), 2,6‐ i Pr 2 ‐C 6 H 3 (DIPP) (L 3 H)] with Zn R 2 ( R = Me, Et) yielded the corresponding bis(phosphinimino)methanide zinc complexes LZnMe [L 2 ( 1 ), L 3 ( 2 )] and LZnEt [L 1 ( 3 ), L 2 ( 4 ), and L 3 ( 5 )]. Complexes 1 – 5 were characterized by heteronuclear NMR ( 1 H, 13 C, 31 P) and IR spectroscopy, elemental analysis, and single‐crystal X‐ray diffraction.