An α‐{P 2 W 18 O 62 } 6– ‐Based Supramolecular Hybrid Inorganic‐Organic Compound with Visible Light‐Driven Photocatalytic Properties | Zendy

Zhu Xiaofei | Zendy; Yang Yu | Zendy; Jiang Ni | Zendy; Li Bo | Zendy; Fu Hai | Zendy; Yin Zifan | Zendy; Yang Jun | Zendy

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An α‐{P 2 W 18 O 62 } 6– ‐Based Supramolecular Hybrid Inorganic‐Organic Compound with Visible Light‐Driven Photocatalytic Properties

Author(s) -

Zhu Xiaofei,

Yang Yu,

Jiang Ni,

Li Bo,

Fu Hai,

Yin Zifan,

Yang Jun

Publication year - 2016

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201600194

Subject(s) - supramolecular chemistry , photocatalysis , visible spectrum , crystallography , crystal structure , materials science , hydrogen bond , powder diffraction , spectroscopy , infrared spectroscopy , diffuse reflection , elemental analysis , chemistry , inorganic chemistry , molecule , catalysis , optics , organic chemistry , physics , optoelectronics , quantum mechanics

The α‐[P 2 W 18 O 62 ] 6– ‐based coordination polymer [Cu 2 (phen) 3 (H 2 O) 3 (P 2 W 18 O 62 )][Cu(phen) 2 (H 2 O)] · 5H 2 O ( 1 ) (phen = phenanthroline), was hydrothermally synthesized and characterized by single‐crystal and powder X‐ray diffraction, IR and UV/Vis diffuse reflection spectroscopy, and elemental analysis. Structural studies reveal that compound 1 exhibits a three‐dimensional (3D) supramolecular structure based on π–π and hydrogen bonding interactions. In addition, visible light driven photocatalytic experiments of compound 1 were also studied.

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