Synthesis and Molecular Structure of  trans ‐[IrCl(NO)(P t Bu 2 H) 2 ]BF 4 | Zendy

Böttcher HansChristian | Zendy; Mies Thomas | Zendy; Mayer Peter | Zendy

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Synthesis and Molecular Structure of trans ‐[IrCl(NO)(P t Bu 2 H) 2 ]BF 4

Author(s) -

Böttcher HansChristian,

Mies Thomas,

Mayer Peter

Publication year - 2016

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201600182

Subject(s) - dichloromethane , diethyl ether , chemistry , yield (engineering) , cyclooctene , crystal structure , medicinal chemistry , stereochemistry , crystallography , catalysis , organic chemistry , materials science , solvent , metallurgy

The synthesis and structural characterization of trans ‐[IrCl(NO)(P t Bu 2 H) 2 ]BF 4 ( 1 ) is reported. The title compound was prepared in good yield in the reaction of in situ‐prepared trans ‐[IrCl(coe)(P t Bu 2 H) 2 ] (coe = cis ‐cyclooctene) with an appropriate amount of nitrosonium tetrafluoridoborate in dichloromethane at room temperature. Single crystals of 1 were grown from dichloromethane/diethyl ether and were analyzed by X‐ray crystallography.

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