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An Organic‐Inorganic Hybrid Based on Keggin‐Type Polyoxometalate and Hypoxanthine: Synthesis, Structure, Stability, and Electrochemistry Properties
Author(s) -
Ma FengJi,
Yuan BaiQing,
Li MengRou,
Li ShuJun,
Zhang ShuangShuang,
Liu LeiLei
Publication year - 2016
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201600178
Subject(s) - polyoxometalate , hypoxanthine , electrochemistry , chemistry , inorganic chemistry , hydrothermal synthesis , keggin structure , thermogravimetry , thermogravimetric analysis , catalysis , thermal stability , hydrothermal circulation , crystallography , organic chemistry , chemical engineering , electrode , enzyme , engineering
The organic‐inorganic hybrid H 5 [Ag 2 (hyp) 2 ] 2 [BW 12 O 40 ] · 9H 2 O ( 1 ) (hpy = hypoxanthine), based on Keggin‐type polyoxometalate and hypoxanthine, was prepared by hydrothermal synthesis and characterized by single‐crystal and powder X‐ray diffraction, IR spectroscopy, elemental analysis, and thermogravimetry. The title compound has a two‐dimensional layer structure constructed by Keggin‐type [BW 12 O 40 ] 5– anion, silver, and the biomolecule hyp. In addition, compound 1 exhibited excellent stability and superior activity in the electro‐catalytic oxidation of glucose.
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