Syntheses, Structures, and Electrochemical Properties of Two Bis‐triazole‐bis‐amide‐based Copper(II) Pyridine‐2,3‐dicarboxylate Coordination Polymers | Zendy

Zhang JuWen | Zendy; Li XiaoLi | Zendy; Kan XiaoMin | Zendy; Liu Ying | Zendy; Liu BinQiu | Zendy

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Syntheses, Structures, and Electrochemical Properties of Two Bis‐triazole‐bis‐amide‐based Copper(II) Pyridine‐2,3‐dicarboxylate Coordination Polymers

Author(s) -

Zhang JuWen,

Li XiaoLi,

Kan XiaoMin,

Liu Ying,

Liu BinQiu

Publication year - 2016

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201600094

Subject(s) - pyridine , electrochemistry , copper , amide , chemistry , triazole , supramolecular chemistry , hydrogen bond , crystallography , coordination polymer , polymer chemistry , polymer , molecule , inorganic chemistry , stereochemistry , medicinal chemistry , crystal structure , organic chemistry , electrode

Abstract. Two bis‐triazole‐bis‐amide‐based copper(II) pyridine‐2,3‐dicarboxylate coordination polymers (CPs), [Cu(2,3‐pydc)(dtb) 0.5 (DMF)] · 2H 2 O ( 1 ) and [Cu(2,3‐pydc)(dth) 0.5 (DMF)] · 2H 2 O ( 2 ) (2,3‐H 2 pydc = pyridine‐2,3‐dicarboxylic acid, dtb = N , N ′‐bis(4 H ‐1,2,4‐triazole)butanamide, and dth = N , N ′‐bis(4 H ‐1,2,4‐triazole)hexanamide), were synthesized under solvothermal conditions. CPs 1 and 2 show similar two‐dimensional (2D) structures. In 1 , the 2,3‐pydc anions bridge the Cu II ions into a one‐dimensional (1D) chain. Such 1D chains are linked by the dtb ligands to form a 2D layer. The adjacent 2D layers are extended into a three‐dimensional (3D) supramolecular architecture by hydrogen‐bonding interactions. The electrochemical properties of 1 and 2 were investigated.

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