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Sorption Behavior and Magnetic Properties of A Heterometallic Organic Framework with Octahedral Cages and One‐Dimensional Channels
Author(s) -
Li Qipeng,
Shen Yanqiong,
Qian Jinjie
Publication year - 2016
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201600033
Subject(s) - octahedron , sorption , microporous material , crystallography , materials science , dabco , acetamide , chemistry , adsorption , crystal structure , organic chemistry , catalysis , composite material
The Zn II ‐Co II organic framework [Me 2 NH 2 ][Zn 2 Co(μ 3 ‐OH)(BTC) 2 (H 2 O)] · 2H 2 O ( FJI‐6 ) (H 3 BTC = 1, 3,5‐benzenetricarboxylic acid and DMA = N.N ′‐dimethyl acetamide), was synthesized and structurally characterized. FJI‐6 shows a three‐dimensional heterometallic microporous framework with coexisting octahedral cages and one‐dimensional channels assembled by Zn 2 Co(μ 3 ‐OH)(CO 2 ) 6 secondary building units. In addition, the sorption behavior and magnetic properties of FJI‐6 were investigated.