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A Room‐Temperature Luminescent AgCF 3 COO Complex Consisting of Cationic Complex Chains and Anionic Guests
Author(s) -
Han Jing,
Di Zhang Yong,
Yu Zhong,
He Xiang,
Jin Bing
Publication year - 2016
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201600030
Subject(s) - cationic polymerization , luminescence , chemistry , molecule , crystallography , crystal structure , solid state , materials science , polymer chemistry , organic chemistry , optoelectronics
Reaction of p ‐phenylenediacetonitrile ( p ‐phda) with AgCF 3 COO afforded the coordination polymer, {[Ag 2 ( p ‐phda) 2 ] [Ag 4 (CF 3 COO) 6 ]} n ( 1 ), where the 1D cationic [Ag 2 ( p ‐phda) 2 ] 2+ chain acts as host and the anionic [Ag 4 (CF 3 COO) 6 ] 2– as guest molecules occupy the channel between neighboring host chains. This is a rare crystal example of AgCF 3 COO complex consisting of cationic complex chains and anionic guests. In addition, complex 1 exhibits luminescence at room temperature in solid state.