A Discrete Nickel Cubane with [Ni 4 O 4 ] Cluster: Synthesis, Structure, and Magnetic Property | Zendy

Zhang QiLong | Zendy; Wu ZhiLei | Zendy; Xu Hong | Zendy; Zhai Bin | Zendy; Wang YuFang | Zendy; Feng GuangWei | Zendy; Huang YaLi | Zendy

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A Discrete Nickel Cubane with [Ni 4 O 4 ] Cluster: Synthesis, Structure, and Magnetic Property

Author(s) -

Zhang QiLong,

Wu ZhiLei,

Xu Hong,

Zhai Bin,

Wang YuFang,

Feng GuangWei,

Huang YaLi

Publication year - 2016

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201500772

Subject(s) - cubane , nickel , thermogravimetric analysis , ferromagnetism , cluster (spacecraft) , crystallography , thermal stability , crystal structure , ligand (biochemistry) , powder diffraction , schiff base , chemistry , diffraction , materials science , single crystal , organic chemistry , physics , condensed matter physics , biochemistry , receptor , optics , computer science , programming language

The tetranuclear nickel cluster {[Ni 4 (L) 4 (C 2 H 5 OH) 4 ] · 7H 2 O} ( 1 ) was synthesized based on the tridentate Schiff base ligand H 2 L = 1‐phenyl‐3‐[(2‐hydroxyphenyl)imino]‐1‐butanone. The structure of 1 was determined by single‐crystal X‐ray diffraction. It exhibits a discrete [Ni 4 O 4 ] cluster. Magnetic studies indicate that ferromagnetic interactions exist within compound 1 . Furthermore, thermogravimetric analysis and PXRD patterns in various solvents reveal thermal and solvent stability of compound 1 .

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