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Copper(I) and Silver(I) Coordination Polymers Based on Rigid Bis(triazole) Ligand: Syntheses, Structures, and Catalytic Properties
Author(s) -
Zhang Xu,
Zhao YanQin,
Dong GuiYing,
Cui GuangHua
Publication year - 2016
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201500686
Subject(s) - chemistry , binodal , cyanide , catalysis , acetonitrile , biphenyl , coordination polymer , infrared spectroscopy , molecule , crystal structure , polymer chemistry , crystallography , ligand (biochemistry) , copper , inorganic chemistry , organic chemistry , biochemistry , receptor , phase diagram , phase (matter)
Two metal coordination polymers, [Cu 2 (btb)(CN) 2 ] n ( 1 ) and [Ag 2 (btb)(muco)] n ( 2 ) [btb = 4, 4′‐bis(1, 2,4‐triazolyl‐1‐yl)‐biphenyl, H 2 muco = trans , trans ‐muconic acid], were synthesized under solvothermal conditions and characterized by elemental analysis, IR spectroscopy, and X‐ray single‐crystal diffraction. Complex 1 exhibits a 1D ladder‐chain structure containing cyanide anions, which are generated in situ by the cleavage of C–C bond of acetonitrile molecules under solvothermal conditions, whereas 2 possesses a rare 3D framework with binodal 4, 6‐connected fsh topology. In addition, the thermal behavior, fluorescence and catalytic properties of the complexes for the degradation of methyl orange in a Fenton‐like process were investigated.