Premium
μ‐Rhodizonato‐1κO,1:2κO′,2κO′′‐tetra(triphenylphosphine)disilver(I): A Molecular Complex with the [C 6 O 6 ] 2– Ligand Template
Author(s) -
Finger Lars H.,
Sundermeyer Jörg
Publication year - 2015
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201500589
Subject(s) - triphenylphosphine , ligand (biochemistry) , transition metal , chemistry , tetra , stereochemistry , crystallography , medicinal chemistry , organic chemistry , catalysis , biochemistry , receptor
The first silver rhodizonate and overall fourth transition metal rhodizonate complex is presented. The title compound shows a so far unobserved coordination mode of the rhodizonate ligand, which is atypically distorted from planarity. The structure discussion is accompanied by a thorough literature review of the hitherto structurally characterized rhodizonate salts and complexes.