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Solvent‐Dependent Synthesis from Layer to Microporous Pillared‐Layer Framework for Selective Sorption of Gas Light Hydrocarbons
Author(s) -
Jiang Zhiqiang,
An Yun,
Zhu Xuejun,
Tian Congxue,
Bai Jing,
Li Yufeng
Publication year - 2015
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201500268
Subject(s) - microporous material , sorption , dimethylacetamide , terephthalic acid , metal organic framework , dimethylamine , chemistry , inorganic chemistry , chemical engineering , adsorption , solvent , materials science , organic chemistry , polyester , engineering
Three metal‐organic frameworks, [Zn 3 (bdc) 3 (DMA) 2 ] ( 1 ) (H 2 bdc = terephthalic acid; DMA = N , N ‐dimethylacetamide), [Zn 3 (bdc) 3 (DMA)(DMPU)] ( 2 ) (DMPU = 1,3‐dimethylpropyleneurea), and [Zn 3 (bdc) 4 (Hdma) 2 ] ( 3 ) [Hdma = protonated dimethylamine (Me 2 NH 2 )] were synthesized by using different solvents. The solvents determine the framework architectures range from layer to microporous pillared‐layer framework. The microporous framework has 8‐connected bcg topology and shows selective sorption ability for gas light hydrocarbons.