A 3D Polyoxometalate‐Based Framework Constructed from Ag/trz Metal‐Organic Ribbons and P 2 W 18  Polyoxoanions: Synthesis, Structure and Electrochemical Properties | Zendy

Wang Xiang | Zendy; Zhang Rui | Zendy; Tian Aixiang | Zendy; Wang Xiuli | Zendy

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A 3D Polyoxometalate‐Based Framework Constructed from Ag/trz Metal‐Organic Ribbons and P 2 W 18 Polyoxoanions: Synthesis, Structure and Electrochemical Properties

Author(s) -

Wang Xiang,

Zhang Rui,

Tian Aixiang,

Wang Xiuli

Publication year - 2015

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201500216

Subject(s) - polyoxometalate , electrochemistry , ligand (biochemistry) , ribbon , metal organic framework , metal , chemistry , crystallography , covalent bond , materials science , inorganic chemistry , organic chemistry , catalysis , composite material , biochemistry , receptor , electrode , adsorption

A Wells‐Dawson Polyoxometalate‐based hybrid, Ag 9 (trz) 3 (Htrz) 4 (H 2 O)(P 2 W 18 O 62 )·3H 2 O ( 1 ) (Htrz = 1,2,4‐1H‐triazole) was hydrothermally synthesized through using trz ligand and silver nitrate in the presence of [P 2 W 18 O 62 ] 6– polyoxoanion. In the 3D framework structure of compound 1 , two kinds of wave‐like Ag/trz chains originated from trz ligands and silver cations are aggregated in a “2+1” mode by {Ag 2 /trz} linkages to result in a 1D Ag/trz metal‐organic ribbon, which is further extended into a 3D framework structure by [P 2 W 18 O 62 ] 6– polyoxoanions through Ag‐O covalent bonds. Additionally, the electrochemical properties of compound 1 have also been investigated.

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