Cd 3 [B 2 P 4 O 14 (OH) 4 ]: A 3D Open‐Framework Cadmium Borophosphate with Unique Twisted 8‐Ring Channels | Zendy

Zhang Dan | Zendy; Feng Yuquan | Zendy; Li Guanghua | Zendy; Yuan Hongming | Zendy

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Cd 3 [B 2 P 4 O 14 (OH) 4 ]: A 3D Open‐Framework Cadmium Borophosphate with Unique Twisted 8‐Ring Channels

Author(s) -

Zhang Dan,

Feng Yuquan,

Li Guanghua,

Yuan Hongming

Publication year - 2015

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201500212

Subject(s) - triclinic crystal system , crystallography , ring (chemistry) , tetrahedron , crystal structure , hydrothermal synthesis , cadmium , hydrothermal circulation , chemistry , bar (unit) , materials science , stereochemistry , physics , geology , organic chemistry , seismology , meteorology

Abstract. The cadmium borophosphate compound Cd 3 [B 2 P 4 O 14 (OH) 4 ] was synthesized under mild hydrothermal conditions. The crystal structure was determined by single‐crystal X‐ray diffraction [triclinic, space group P $\bar{1}$ (no. 2), a = 5.4362(11) Å, b = 8.2190(16) Å, c = 8.3918(17) Å, and α = 111.87(3)°, β = 104.63(3)°, γ = 90.73(3)°, V = 334.29(12) Å 3 and Z = 1]. The 3D open framework of the title compound is constructed from BO 3 (OH) tetrahedra and 2D layers along the [100] direction. The resulting framework contains twisted eight‐membered rings that form 1D channels.

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