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Cd 3 [B 2 P 4 O 14 (OH) 4 ]: A 3D Open‐Framework Cadmium Borophosphate with Unique Twisted 8‐Ring Channels
Author(s) -
Zhang Dan,
Feng Yuquan,
Li Guanghua,
Yuan Hongming
Publication year - 2015
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201500212
Subject(s) - triclinic crystal system , crystallography , ring (chemistry) , tetrahedron , crystal structure , hydrothermal synthesis , cadmium , hydrothermal circulation , chemistry , bar (unit) , materials science , stereochemistry , physics , geology , organic chemistry , seismology , meteorology
Abstract. The cadmium borophosphate compound Cd 3 [B 2 P 4 O 14 (OH) 4 ] was synthesized under mild hydrothermal conditions. The crystal structure was determined by single‐crystal X‐ray diffraction [triclinic, space group P $\bar{1}$ (no. 2), a = 5.4362(11) Å, b = 8.2190(16) Å, c = 8.3918(17) Å, and α = 111.87(3)°, β = 104.63(3)°, γ = 90.73(3)°, V = 334.29(12) Å 3 and Z = 1]. The 3D open framework of the title compound is constructed from BO 3 (OH) tetrahedra and 2D layers along the [100] direction. The resulting framework contains twisted eight‐membered rings that form 1D channels.