Premium
Synthesis and Characterization of Bis(2‐iminopyrrolyl) Iron(II) Complexes by N–H Bond Activation
Author(s) -
Jiao Guili,
Zhu Gengyu,
Zhang Shumiao,
Sun Hongjian
Publication year - 2015
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201500157
Subject(s) - chemistry , crystallography , characterization (materials science) , mechanism (biology) , single crystal , crystal structure , stereochemistry , materials science , nanotechnology , philosophy , epistemology
The reactions of 2‐iminopyrroles 1 – 3 with Fe(PMe 3 ) 4 afforded the N–H activated bis(2‐iminopyrrolyl) iron(II) complexes 4 – 6 . The structures of compounds 4 – 6 were determined by single‐crystal X‐ray diffraction. The formation mechanism of complexes 4 – 6 was discussed.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom