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Synthesis, Crystal Structures, and Luminescent Properties of Two Complexes based on 5‐ tert ‐Butylisophthalic Acid and 1, 2‐Bis(4‐pyridyl) Ethane
Author(s) -
Xu Bo,
Guo Shan,
Li Zhi Wang,
Li Cun Cheng
Publication year - 2015
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201500132
Subject(s) - luminescence , crystal structure , hydrothermal circulation , crystallography , chemistry , hydrothermal reaction , topology (electrical circuits) , coordination polymer , hydrothermal synthesis , diffraction , photoluminescence , single crystal , polymer , type (biology) , layer (electronics) , materials science , physics , chemical engineering , organic chemistry , mathematics , optoelectronics , optics , combinatorics , engineering , ecology , biology
Abstract. Two coordination polymers, namely, [Zn(bpe) 0.5 (Htbip)(tbip) 0.5 ] · H 2 O ( 1 ) and [Cd(bpe) 0.5 (tbip)] ( 2 ) [H 2 tbip = 5‐ tert ‐butylisophthalic acid and bpe = 1, 2‐ bis(4‐pyridyl) ethane] were synthesized through hydrothermal reactions. Single‐crystal X‐ray diffraction analysis reveals that complex 1 presents a three‐dimensional (3D) six‐connected uninodal structure with the type of topology of svi‐x/ I 4/ mcm → Ibam , whereas complex 2 holds a 2D 4 4 ‐ sql layer structure. Moreover, the photoluminescent properties of the complexes at room temperature were investigated.