Crystal Structure of a Commercial Product Called  Lead Cyanurate | Zendy

Dolabdjian Konstantin | Zendy; Ströbele Markus | Zendy; Meyer H.Jürgen | Zendy

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Crystal Structure of a Commercial Product Called Lead Cyanurate

Author(s) -

Dolabdjian Konstantin,

Ströbele Markus,

Meyer H.Jürgen

Publication year - 2015

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201500103

Subject(s) - monoclinic crystal system , cyanuric acid , crystal structure , crystallography , lead oxide , powder diffraction , ion , chemistry , crystal (programming language) , materials science , organic chemistry , melamine , computer science , programming language

The reaction of PbO with cyanuric acid was reported to give lead cyanurate , described in the literature as Pb 3 (O 3 C 3 N 3 ) 2 · 2H 2 O. Crystalline powders were prepared and investigated by X‐ray powder diffraction, yielding a monoclinic crystal structure (space group Cc, a = 16.6217(1) Å, b = 6.7161(1) Å, c = 12.4308(1) Å, β = 117.567(1)°). The structure solution and refinement yielded lead oxide isocyanurate corresponding to the formula Pb 3 O 2 (O 3 C 3 N 3 H 2 ) 2 , with a layered arrangement of [Pb 3 O 2 ] 2+ ions and monovalent isocyanurate anions in an alternating fashion.

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