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Organometallic Lewis Acids, Part LIX [1] Pentacarbonylrhenium Complexes with Phosphorus Tricyanide and Dicyanophosphide
Author(s) -
Sacher Wolfgang,
Schmidpeter Alfred,
Beck Wolfgang
Publication year - 2015
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201500068
Subject(s) - chemistry , rhenium , lewis acids and bases , phosphorus , medicinal chemistry , stereochemistry , inorganic chemistry , catalysis , organic chemistry
Abstract The addition of Re(CO) 5 + [as Re(CO) 5 FBF 3 ] to P(CN) 3 and to P(CN) 2 – affords the complexes [Re(CO) 5 ] 3 P(CN) 3 (BF 4 ) 3 and Re(CO) 5 P(CN) 2 , respectively. The spectroscopic data indicate that Re(CO) 5 + is coordinated to each of the three cyano groups of P(CN) 3 to give {P[C≡N‐Re(CO) 5 ] 3 }[BF 4 ] 3 , whereas the pseudohalide P(CN) 2 – is bonded to the rhenium cation through the phosphorus atom.