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Synthesis, Structure, and Magnetic Properties of a Mn 4 Cluster derived from Benzimidazole‐Alcohol Ligands
Author(s) -
Wang Feng,
Ding Yu,
Guo Liangui,
Du Jun,
Zhang Xiaowen
Publication year - 2015
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201500064
Subject(s) - benzimidazole , tetrahedron , cluster (spacecraft) , crystal structure , crystallography , magnetic susceptibility , chemistry , ion , molecule , alcohol , ground state , stereochemistry , topology (electrical circuits) , physics , atomic physics , organic chemistry , mathematics , programming language , combinatorics , computer science
The synthesis, crystal structure, and magnetic properties of a [Mn III 3 Mn II (μ 3 ‐O)(mbp) 3 (OAc) 3 ] · 4H 2 O ( 1 ) [H 2 mbp = 2‐(1H‐benzimidazol‐2‐yl)‐2‐ methylpropane‐1,3‐diol] cluster are reported herein. Mn ions in compound 1 have a tetrahedron topology. Solid‐state direct current and alternating current magnetic susceptibility measurements on compound 1 reveal a ground state with S T = 7/2 as well as the probable single‐molecule magnetic behavior.