Synthesis and X‐ray Crystal Structures of Zinc Dichloride Complexes Supported by a  β ‐Diimine Ligand | Zendy

Scheiper Christoph | Zendy; Naglav Dominik | Zendy; Bläser Dieter | Zendy; Wölper Christoph | Zendy; Schulz Stephan | Zendy

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Synthesis and X‐ray Crystal Structures of Zinc Dichloride Complexes Supported by a β ‐Diimine Ligand

Author(s) -

Scheiper Christoph,

Naglav Dominik,

Bläser Dieter,

Wölper Christoph,

Schulz Stephan

Publication year - 2015

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201500046

Subject(s) - diimine , tautomer , zinc , chemistry , imine , crystallography , ligand (biochemistry) , crystal structure , spectroscopy , single crystal , elemental analysis , nuclear magnetic resonance spectroscopy , stereochemistry , inorganic chemistry , organic chemistry , catalysis , physics , biochemistry , receptor , quantum mechanics

β ‐Diimine zinc dichloride complexes [CH 2 {C(Me)NAr} 2 ]ZnCl 2 [Ar = Mes ( 1 ), Dipp ( 2 )] were obtained from the reactions of ZnCl 2 with the corresponding β ‐iminoamines [ArN(H)C(Me)CHC(Me)NAr]. Complexes 1 and 2 were characterized by multinuclear NMR ( 1 H, 13 C) and IR spectroscopy, elemental analyses as well as by single‐crystal X‐ray diffraction. The energy differences between the enamine‐imine tautomers of the β ‐iminoamines were quantified by quantum chemical calculations.

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