Construction and Properties of Two MOFs Based on 2‐ p ‐Bromophenyl Imidazole Dicarboxylate | Zendy

Zhu YongChao | Zendy; Ren Xue | Zendy; Wang Jing | Zendy; Li Gang | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Construction and Properties of Two MOFs Based on 2‐ p ‐Bromophenyl Imidazole Dicarboxylate

Author(s) -

Zhu YongChao,

Ren Xue,

Wang Jing,

Li Gang

Publication year - 2015

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201400612

Subject(s) - imidazole , ligand (biochemistry) , crystallography , coordination polymer , polymer , crystal structure , metal , single crystal , metal organic framework , materials science , diffraction , chemistry , stereochemistry , organic chemistry , physics , metallurgy , optics , biochemistry , receptor , adsorption

To further explore the coordination ability of an multi‐functional ligand 2‐( p ‐bromophenyl)‐1 H ‐imidazole‐4,5‐dicarboxylic acid ( p ‐BrPhH 3 IDC), two metal‐organic frameworks [Mn(μ 2 ‐ p ‐BrPhH 2 IDC) 2 ] n ( I ) and {[Pb(μ 2 ‐ p ‐BrPhH 2 IDC) 2 ] · H 2 O} n ( II ) were synthesized under hydro(solvo)thermal conditions and structurally characterized by elemental analyses, IR spectroscsopy, and single‐crystal X‐ray diffraction. Polymer I shows a 2D sheet structure. In polymer II , 1D octagonal channels are connected by the organic ligands to form a 3D architecture. Furthermore, the thermal characteristics of the two polymers and the coordination features of p ‐BrPhH 3 IDC were investigated.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research