Reactivity with Amines of Bis(cyanamide) and Bis(cyanoguanidine) Complexes of the Iron Triad | Zendy

Albertin Gabriele | Zendy; Antoniutti Stefano | Zendy; Caia Alfonso | Zendy; Castro Jesús | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Reactivity with Amines of Bis(cyanamide) and Bis(cyanoguanidine) Complexes of the Iron Triad

Author(s) -

Albertin Gabriele,

Antoniutti Stefano,

Caia Alfonso,

Castro Jesús

Publication year - 2015

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201400591

Subject(s) - cyanamide , chemistry , amine gas treating , medicinal chemistry , reactivity (psychology) , ligand (biochemistry) , crystal structure , stereochemistry , crystallography , organic chemistry , medicine , biochemistry , alternative medicine , receptor , pathology

Treatment of bis(cyanamide) [M(N≡CNEt 2 ) 2 L 4 ](BPh 4 ) 2 and bis(cyanoguanidine) [ M {N≡CN(H)C(NH 2 )=NH} 2 L 4 ](BPh 4 ) 2 complexes [ M = Fe, Ru, Os; L = P(OEt) 3 ] with an excess of amine R NH 2 ( R = n Pr, i Pr) affords mixed‐ligand complexes with cyanamide and amine [ M (NH 2 R)(N≡CNEt 2 )L 4 ](BPh 4 ) 2 ( 1a – 5a ) and [ M (NH 2 R){N≡CN(H)C(NH 2 )=NH}L 4 ](BPh 4 ) 2 ( 1b , 2b ). The complexes were characterized by spectroscopy and X‐ray crystal structure determination of [ M (NH 2 i Pr)(N≡CNEt 2 ){P(OEt) 3 } 4 ](BPh 4 ) 2 [ M = Ru ( 3a ), Os ( 5a )].

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research