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Phosphorus Rich d 10 Ion Polyphosphides and Selected Materials
Author(s) -
Bawohl Melanie,
Nilges Tom
Publication year - 2015
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201400577
Subject(s) - phosphorene , ternary operation , phosphorus , adduct , black phosphorus , metal halides , ion , halide , transition metal , inorganic chemistry , chemistry , materials science , nanotechnology , organic chemistry , catalysis , computer science , optoelectronics , monolayer , programming language
Polyphosphides composed by late transition metal ions with closed d 10 shells are subject of this review. Recent progress has been made during the past years in this field and many new compounds have been discovered. The spectrum of compounds extends from classical binary and ternary compounds, adduct phases of metal halides and molecular species to composites of intermetalloid clusters and molecular anion substructures. Phosphorus is highly reactive to late transition metals forming d 10 ions and they entirely react to a plenthora of materials. Only a handful of elements do not form binary compounds with phosphorus and the number is decreasing. This review is focussed on synthetic procedures and the structure property relations of d 10 ion polyphosphides. A brief overview is also given to the progress in phosphorus allotrope chemistry and their perspectives and applications. Especially black phosphorus as active material for batteries and its de‐laminated form “phosphorene” is added.