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Syntheses and Characterization of Three New Compounds Based on Terephthalate and 2‐(2‐Pyridin‐4‐yl‐vinyl)benzimidazole Ligands
Author(s) -
Xia ChangKun,
Wei Chao,
Wu YunLong,
Wu Fan,
Yang Shen,
Ma JiaLi
Publication year - 2015
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201400528
Subject(s) - denticity , benzimidazole , supramolecular chemistry , hydrogen bond , coordination sphere , crystal structure , crystallography , chemistry , coordination complex , molecule , stereochemistry , metal , organic chemistry
Three new compounds based on H 2 BDC and PyBImE [H 2 BDC = 1,4‐benzenedicarboxylatic acid, PyBImE = 2‐(2‐pyridin‐4‐yl‐vinyl)benzimidazole], namely, [Co(PyBImE)(BDC)(H 2 O) 2 ] ( 1 ), [Co(PyBImE) 2 (HBDC)(BDC) 0.5 ] ( 2 ), and [(HPyBImE) + · (BDC) 2 – 0.5 · (H 2 BDC) 0.5 ] ( 3 ), were synthesized by hydrothermal methods and characterized by single‐crystal X‐ray diffraction. Compound 1 is a one‐dimensional chain bridged by terephthalate in a bis(monodentate) fashion. In the complex the nitrogen atom from N BIm and the coordination water molecule complete the coordination sphere. In complex 2 , the dinuclear cobalt units are bridged by terephthalate in a bis(bidentate) fashion into a one‐dimensional chain, but different from complex 1 , the nitrogen atom from N Py and the oxygen atom from hydrogenterephthalate complete the coordination sphere. Complex 3 is a co‐crystal with PyBImE and H 2 BDC in a 1:1 ratio and the transfer of hydrogen atoms leads the complex into a salt. Interesting supramolecular structures are shown due to the hydrogen bonding as well as π ··· π interactions in the three complexes. Thermal and magnetic properties of 1 and 2 were also studied.