1  ∞ [Pr(BSB) 3 (py) 2 ]: A Lanthanide Bis(salicylato)borate at the Junction between Solvothermal and Ionothermal Conditions | Zendy

Zottnick Sven H. | Zendy; Sorg Jens R. | Zendy; Sprenger Jan A. P. | Zendy; Finze Maik | Zendy; MüllerBuschbaum Klaus | Zendy

Premium

1 ∞ [Pr(BSB) 3 (py) 2 ]: A Lanthanide Bis(salicylato)borate at the Junction between Solvothermal and Ionothermal Conditions

Author(s) -

Zottnick Sven H.,

Sorg Jens R.,

Sprenger Jan A. P.,

Finze Maik,

MüllerBuschbaum Klaus

Publication year - 2015

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201400498

Subject(s) - boron , ionic liquid , lanthanide , pyridine , anhydrous , crystallization , halide , solvothermal synthesis , inorganic chemistry , sodium , chemistry , ion , materials science , catalysis , medicinal chemistry , organic chemistry

A coordination polymer of the formula 1 ∞ [Pr(BSB) 3 (py) 2 ] constituted of bis(salicylato)borate anions ([BSB] – ) and Pr 3+ was synthesized as single crystals from the sodium salt under solvothermal conditions in pyridine. The formation of sodium chloride is a driving force valid for a reaction under solvothermal and ionothermal conditions using the ionic liquid (IL) 1‐ethyl‐3‐methylimidazolium‐bis(salicylato)borate [EMIM][BSB]. For the formation of isoconstitutional compounds the latter reaction also requires a certain amount of pyridine, which is beneficial for crystallization. In addition, a different precursor has to be employed: whilst the solvothermal reaction can be carried out with the anhydrous halide Ln Cl 3 , the IL‐based reaction is only successful with the complex [ Ln Cl 3 (py) 4 ] as precursor.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research