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Organic Cation and Complex Cation‐Stabilized (Poly‐)Selenides, [Cation] x (Se y ) z : Diversity in Structures and Properties
Author(s) -
Thiele Günther,
Vondung Lisa,
Donsbach Carsten,
Pulz Susanne,
Dehnen Stefanie
Publication year - 2014
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201400457
Subject(s) - selenide , chemistry , characterization (materials science) , crystal structure , crystallography , inorganic chemistry , materials science , selenium , organic chemistry , nanotechnology
Abstract Based on the synthesis and characterization of a series of new (poly‐)selenide salts, a classification of anionic (poly‐)selenide‐containing compounds is proposed. The new compounds were categorized according to these classes. Synthetic approaches of organic cation‐stabilized (poly‐)selenide compounds that have been already known from literature are reviewed, along with the crystal structures of new compounds and some spectroscopic data, and an experimental and theoretical approach towards dichroism observed in some of the triselenides.