Hydrothermal Synthesis, Crystal Structures, and Luminescent Properties of Two Cadmium(II) Coordination Polymers Based on Dicarboxylate and Imidazole‐Containing Coligands | Zendy

Yang Bin | Zendy; Chen Ning | Zendy; Tse KwongMing | Zendy; Lee HeowPueh | Zendy

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Hydrothermal Synthesis, Crystal Structures, and Luminescent Properties of Two Cadmium(II) Coordination Polymers Based on Dicarboxylate and Imidazole‐Containing Coligands

Author(s) -

Yang Bin,

Chen Ning,

Tse KwongMing,

Lee HeowPueh

Publication year - 2015

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201400398

Subject(s) - luminescence , imidazole , hydrothermal circulation , cadmium , benzene , coordination polymer , polymer , crystal structure , chemistry , hydrothermal synthesis , crystallography , materials science , stereochemistry , organic chemistry , chemical engineering , optoelectronics , engineering

In this paper, two cadmium(II) coordination polymers [Cd(sdb)(bib)] n ( 1 ) and {[Cd 2 (pda) 2 (bib) 2 ] · 0.5H 2 O} n ( 2 ) [H 2 sdb = 4,4′‐sulfonyl‐dicarboxylic acid, H 2 pda = 1,3‐phenylenediacetic acid, and bib = 1,4‐bis(1‐imidazolyl) benzene] were synthesized and characterized by hydrothermal methods. Complex 1 displays a 3,5‐connected topological net and complex 2 shows a 4‐connected non‐interpenetrated pcu framework. Furthermore, the luminescent properties for complexes 1 and 2 were investigated.

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